Scientists at Tokyo Institute of Technology examined the mechanisms behind the resistance at the electrode-electrolyte interface of all-solid-state batteries. Their findings will aid in the development of much better Li-ion batteries with very fast charge/discharge rates.

Designing and improving lithium-ion (Li-ion) batteries is crucial for extending the limits of modern electronic devices and electric vehicles because Li-ion batteries are virtually ubiquitous.

Scientists at Tokyo Institute of Technology (Tokyo Tech), led by Prof. Taro Hitosugi, had previously reported a new type of all-solid-state battery, also based on lithium ions, which overcame one of the major problems of those batteries: high resistance at the interface between the electrodes and the electrolytes that limits fast charging/discharging.

Although the devices they produced were very promising and were much better than conventional Li-ion batteries in some regards, the mechanism behind the reduced interface resistance was unclear. It has been difficult to analyze the buried interfaces in all-solid-state batteries without damaging their layers.

Therefore, Hitosugi and his team of researchers again investigated all-solid-state batteries to shed light on this topic. They suspected that crystallinity (which indicates how well-ordered and periodic a solid is) at the electrode-electrolyte interface played a key role in defining interface resistance.

To prove this, they fabricated two different all-solid-state batteries composed of electrode and electrolyte layers using a pulsed laser deposition technique.

One of these batteries had presumably high crystallinity at the electrode-electrolyte interface, whereas the other one did not. Confirming this was possible by using a novel technique called X-ray crystal truncation-rod scattering analysis. "X-rays can reach the buried interfaces without destroying the structures," explains Hitosugi.

Based on their results, the team concluded that a highly crystalline electrode-electrolyte interface resulted in low interface resistance, yielding a high-performance battery.

By analyzing the microscopic structure of the interfaces of their batteries, they proposed a plausible explanation for the increased resistance of batteries with less crystalline interfaces. Lithium ions are stuck at the less crystalline interfaces, hindering ion conductivity.

"Controlled fabrication of the electrolyte/electrode interface is crucial to obtain low interface resistance," explains Hitosugi. The development of theories and simulations to further understand the migration of Li ions will be crucial for finally achieving useful and improved batteries for all kinds of devices based on electrochemistry.

Research paper

Related Links
Tokyo Institute of Technology
Powering The World in the 21st Century at Energy-Daily.com

Tweet

Thanks for being here; We need your help. The SpaceDaily news network continues to grow but revenues have never been harder to maintain. With the rise of Ad Blockers, and Facebook - our traditional revenue sources via quality network advertising continues to decline. And unlike so many other news sites, we don't have a paywall - with those annoying usernames and passwords. Our news coverage takes time and effort to publish 365 days a year. If you find our news sites informative and useful then please consider becoming a regular supporter or for now make a one off contribution.
SpaceDaily Contributor $5 Billed Once credit card or paypal		SpaceDaily Monthly Supporter $5 Billed Monthly paypal only

The shape of things to come: Flexible, foldable supercapacitors for energy storage
London, UK (SPX) Nov 23, 2018
A team of researchers from the Plasma Physics Research Centre, Science and Research Branch of Islamic Azad University in Tehran, Iran, have discovered a way of making paper supercapacitors for electricity storage, according to a new study published in the journal Heliyon . At one sheet thick, these new supercapacitors can bend, fold, flex, and still hold electricity. The term "supercapacitors" is reserved for devices that hold over 10 times as much energy per unit volume as a traditional capacitor ... read more